Regional assessment of status and trends in PAH concentrations in sediment

  • Overview
  • Summary of individual time series results
  • Regional assessment - methods
  • Regional assessment - availability of time series
  • Regional trends
  • Regional status compared to the Effects Range Low (ERL)
  • Regional status compared to the Background Assessment Concentration (BAC)
  • PAH profiles

Overview

The 2024 OSPAR CEMP assessment describes the status and trends of contaminant concentrations in biota and sediment at monitoring stations in the OSPAR area. Assessments are made for a large number of time series, each of a single contaminant in a single species and tissue (for biota) or matrix (for sediment) at a single monitoring station. This document is one of a series that synthesises the results of the individual time series to assess status and trends at the MIME regional level. In particular, it considers PAH concentrations in sediment, where the PAHs are NAP, ACNLE, ACNE, FLE, PA, ANT, DBT, FLU, PYR, BAA, CHR, BAP, BEP, BBKF, DBAHA, PER, BGHIP, ICDP. For simplicity, the term ‘region’ is used throughout to describe MIME regions. OSPAR regions are always referred to as such.

The regional status assessments presented in this document are integrated with regional status assessments for other contaminants and biological effects using the CHASE approach. Details can be found here.

The following sections:

  • summarise the individual time series results
  • describe the methods used to combine the individual time series results to estimate regional status and trends
  • present the estimates of regional trends
  • present the estimates of regional status


Summary of individual time series results

A time series of PAH concentrations is assessed for status if:

  • there is at least one year with data in the period 2017 to 2022
  • there are at least three years of data over the whole time series
  • a parametric model can be fitted to the data and used to estimate the mean concentration in the final monitoring year (or, occasionally, if a non-parametric test of status is applied)

The conditions are more stringent for trends. Specifically, a time series is assessed for trends if:

  • there is at least one year with data in the period 2017 to 2022
  • there are at least five years of data over the whole time series
  • a parametric model can be fitted to the data and used to estimate the trend in mean concentration

Note that all trend assessments for individual time series and most status assessments are based on the fit of a parametric model. This is important because only the parametric results are passed into the regional assessments in the following sections. 8 of the 3581 PAH time series were assessed for status using a non-parametric test.

Note also that time series from the Iberian Coast are included even though the last data year is 2016. This is for continuity: samples were collected in 2022 but have yet to be analysed and reported.

The first tab below shows all the monitoring stations where there are individual time series assessments of trend or status for PAHs. The purple circles are stations where there is a trend assessment for at least one PAH, and the light blue cirles are stations where there are only status assessments.

The next set of tabs show the trend and status assessments for each PAH in turn. The colours have the following meaning:

  • blue: the mean concentration is significantly (p < 0.05) below the Background Assessment Concentration (BAC)
  • green: the mean concentration is significantly (p < 0.05) below the Effects Range Low (ERL)
  • orange: there is no ERL and the mean concentration is not significantly below the BAC
  • red: the mean concentration is not signficantly below the ERL
  • black: there are no assessment criteria available

And the shapes have the following meaning:

  • downward triangle: the mean concentration is significantly decreasing (p < 0.05)
  • circle: there is no significant change in mean concentration (p > 0.05) or there are too few years to test for trends
  • upward triangle: the mean concentration is significantly increasing (p < 0.05)

The final set of tabs give:

  • the number of time series with upwards, downwards or no trend in each MIME and OSPAR region
  • the same information presented as proportions
  • the number of time series with blue, green, orange or red status in each MIME and OSPAR region
  • the same information presented as proportions

Note that only eleven of the PAHs have assessment criteria: NAP, PA, ANT, DBT, FLU, PYR, BAA, CHR, BAP, BGHIP, ICDP. Of these, DBT only has an ERL and BGHIP and ICDP only have a BAC. (NAP has an ERL and a BAC in all regions apart from the Iberian Coast and Gulf of Cadiz, where only the ERL applies.)


Stations


NAP


ACNLE


ACNE


FLE


PA


ANT


DBT


FLU


PYR


BAA


CHR


BAP


BEP


BBKF


DBAHA


PER


BGHIP


ICDP


Trend summary (numbers)

Number of time series with upwards, downwards or no trend by MIME and OSPAR region

OSPAR region MIME region status NAP ACNLE ACNE FLE PA ANT DBT FLU PYR BAA CHR BAP BEP BBKF DBAHA PER BGHIP ICDP total
2 Northern North Sea upward trend 2 0 0 0 0 1 0 1 1 1 1 1 1 0 0 1 1 1 12
no trend 10 7 12 12 14 12 11 13 13 13 13 13 12 13 15 13 12 14 222
downward trend 4 2 1 4 3 2 3 3 3 3 3 3 4 4 2 3 4 2 53
Southern North Sea upward trend 6 1 1 3 6 12 0 2 2 2 0 0 0 0 0 0 0 1 36
no trend 27 12 20 29 42 40 0 46 39 42 44 47 25 35 48 13 40 39 588
downward trend 3 0 6 4 10 4 0 11 14 13 13 10 9 12 6 2 16 17 150
Channel upward trend 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
no trend 2 3 3 3 2 2 1 9 2 3 2 5 1 6 3 1 4 4 56
downward trend 1 0 0 0 1 1 1 1 1 0 1 1 2 2 0 2 1 0 15
total upward trend 8 1 1 3 6 13 0 3 3 3 1 1 1 0 0 1 1 2 48
no trend 39 22 35 44 58 54 12 68 54 58 59 65 38 54 66 27 56 57 866
downward trend 8 2 7 8 14 7 4 15 18 16 17 14 15 18 8 7 21 19 218
3 Irish and Scottish West Coast upward trend 0 0 0 0 1 0 0 1 2 0 1 1 1 1 1 0 1 1 11
no trend 6 4 5 6 6 7 5 6 5 6 5 6 6 6 6 6 6 6 103
downward trend 1 0 0 0 0 0 0 0 0 1 1 0 0 0 0 1 0 0 4
Irish Sea upward trend 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 1 2
no trend 10 6 12 11 13 10 7 13 11 12 12 12 10 11 12 6 13 11 192
downward trend 5 5 1 1 2 5 2 2 4 3 2 3 4 3 3 7 2 3 57
Celtic Sea upward trend 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
no trend 0 1 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 1 3
downward trend 1 0 1 1 1 1 0 1 1 1 1 1 1 1 0 1 1 0 14
total upward trend 0 0 0 0 1 0 0 1 2 0 1 1 2 1 1 0 1 2 13
no trend 16 11 17 17 19 17 12 19 16 18 17 18 16 17 19 12 19 18 298
downward trend 7 5 2 2 3 6 2 3 5 5 4 4 5 4 3 9 3 3 75
4 Gulf of Cadiz upward trend 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 1
no trend 0 0 0 0 12 11 0 9 9 12 12 12 10 13 7 0 12 7 126
downward trend 0 0 0 0 1 1 0 4 4 1 1 1 3 0 0 0 1 6 23
total upward trend 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 1
no trend 0 0 0 0 12 11 0 9 9 12 12 12 10 13 7 0 12 7 126
downward trend 0 0 0 0 1 1 0 4 4 1 1 1 3 0 0 0 1 6 23


Trend summary (proportions)

Proportion of time series with upwards, downwards or no trend by MIME and OSPAR region

OSPAR region MIME region status NAP ACNLE ACNE FLE PA ANT DBT FLU PYR BAA CHR BAP BEP BBKF DBAHA PER BGHIP ICDP total
2 Northern North Sea upward trend 13 0 0 0 0 7 0 6 6 6 6 6 6 0 0 6 6 6 4
no trend 62 78 92 75 82 80 79 76 76 76 76 76 71 76 88 76 71 82 77
downward trend 25 22 8 25 18 13 21 18 18 18 18 18 23 24 12 18 23 12 19
Southern North Sea upward trend 17 8 4 8 10 21 3 4 3 0 0 0 0 0 0 0 2 5
no trend 75 92 74 81 73 72 78 71 74 77 82 74 74 89 87 71 68 76
downward trend 8 0 22 11 17 7 19 25 23 23 18 26 26 11 13 29 30 19
Channel upward trend 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
no trend 67 100 100 100 67 67 50 90 67 100 67 83 33 75 100 33 80 100 79
downward trend 33 0 0 0 33 33 50 10 33 0 33 17 67 25 0 67 20 0 21
total upward trend 14 4 2 5 8 18 0 4 4 4 1 1 2 0 0 3 1 3 4
no trend 71 88 82 80 74 73 75 79 72 75 77 81 70 75 89 77 72 73 77
downward trend 15 8 16 15 18 9 25 17 24 21 22 18 28 25 11 20 27 24 19
3 Irish and Scottish West Coast upward trend 0 0 0 0 14 0 0 14 29 0 14 14 14 14 14 0 14 14 9
no trend 86 100 100 100 86 100 100 86 71 86 72 86 86 86 86 86 86 86 87
downward trend 14 0 0 0 0 0 0 0 0 14 14 0 0 0 0 14 0 0 4
Irish Sea upward trend 0 0 0 0 0 0 0 0 0 0 0 0 7 0 0 0 0 7 1
no trend 67 55 92 92 87 67 78 87 73 80 86 80 66 79 80 46 87 73 76
downward trend 33 45 8 8 13 33 22 13 27 20 14 20 27 21 20 54 13 20 23
Celtic Sea upward trend 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
no trend 0 100 0 0 0 0 0 0 0 0 0 0 0 100 0 0 100 18
downward trend 100 0 100 100 100 100 100 100 100 100 100 100 100 0 100 100 0 82
total upward trend 0 0 0 0 4 0 0 4 9 0 5 4 9 5 4 0 4 9 3
no trend 70 69 89 89 83 74 86 83 69 78 77 78 69 77 83 57 83 78 77
downward trend 30 31 11 11 13 26 14 13 22 22 18 18 22 18 13 43 13 13 20
4 Gulf of Cadiz upward trend 0 8 0 0 0 0 0 0 0 0 0 0 1
no trend 92 84 69 69 92 92 92 77 100 100 92 54 84
downward trend 8 8 31 31 8 8 8 23 0 0 8 46 15
total upward trend 0 8 0 0 0 0 0 0 0 0 0 0 1
no trend 92 84 69 69 92 92 92 77 100 100 92 54 84
downward trend 8 8 31 31 8 8 8 23 0 0 8 46 15


Status summary (numbers)

Number of time series with each status by MIME and OSPAR region

OSPAR region MIME region status NAP PA ANT DBT FLU PYR BAA CHR BAP BGHIP ICDP total
2 Northern North Sea blue 13 12 12 0 11 10 10 10 11 12 9 110
green 4 5 7 21 10 11 11 11 10 0 0 90
orange 0 0 0 0 0 0 0 0 0 9 12 21
red 4 4 2 0 0 0 0 0 0 0 0 10
Southern North Sea blue 2 9 2 0 3 3 4 3 18 66 73 183
green 61 77 87 5 88 87 87 89 73 0 0 654
orange 0 0 0 0 0 0 0 0 0 25 19 44
red 9 6 3 0 1 0 1 0 1 0 0 21
Channel blue 3 6 2 0 6 4 2 4 7 14 23 71
green 21 30 25 5 37 41 34 40 39 0 0 272
orange 0 0 0 0 0 0 0 0 0 36 27 63
red 10 15 18 0 8 6 15 7 5 0 0 84
total blue 18 27 16 0 20 17 16 17 36 92 105 364
green 86 112 119 31 135 139 132 140 122 0 0 1016
orange 0 0 0 0 0 0 0 0 0 70 58 128
red 23 25 23 0 9 6 16 7 6 0 0 115
3 Irish and Scottish West Coast blue 1 4 5 0 6 5 4 3 6 8 8 50
green 8 5 4 6 3 4 4 6 3 0 0 43
orange 0 0 0 0 0 0 0 0 0 1 1 2
red 0 0 0 0 0 0 1 0 0 0 0 1
Irish Sea blue 0 0 0 0 0 0 0 0 0 4 6 10
green 18 16 17 12 18 17 17 17 17 0 0 149
orange 0 0 0 0 0 0 0 0 0 15 13 28
red 1 3 2 0 1 2 2 2 2 0 0 15
Celtic Sea blue 0 1 0 0 1 1 1 1 2 2 3 12
green 3 4 3 1 4 4 4 4 3 0 0 30
orange 0 0 0 0 0 0 0 0 0 3 2 5
red 1 0 1 0 0 0 0 0 0 0 0 2
total blue 1 5 5 0 7 6 5 4 8 14 17 72
green 29 25 24 19 25 25 25 27 23 0 0 222
orange 0 0 0 0 0 0 0 0 0 19 16 35
red 2 3 3 0 1 2 3 2 2 0 0 18
4 Iberian Coast blue 0 4 3 0 7 8 5 10 11 10 9 67
green 0 22 20 0 22 23 20 19 20 0 0 146
orange 0 0 0 0 0 0 0 0 0 25 25 50
red 0 9 10 0 6 4 9 6 4 0 0 48
Gulf of Cadiz blue 0 18 2 0 18 16 13 18 16 14 18 133
green 0 6 21 0 6 8 11 6 7 0 0 65
orange 0 0 0 0 0 0 0 0 0 12 7 19
red 0 1 1 0 1 1 1 1 1 0 0 7
total blue 0 22 5 0 25 24 18 28 27 24 27 200
green 0 28 41 0 28 31 31 25 27 0 0 211
orange 0 0 0 0 0 0 0 0 0 37 32 69
red 0 10 11 0 7 5 10 7 5 0 0 55


Status summary (proportions)

Proportion of time series with each status by MIME and OSPAR region

OSPAR region MIME region status NAP PA ANT DBT FLU PYR BAA CHR BAP BGHIP ICDP total
2 Northern North Sea blue 62 57 57 0 52 48 48 48 52 57 43 48
green 19 24 33 100 48 52 52 52 48 0 0 39
orange 0 0 0 0 0 0 0 0 0 43 57 9
red 19 19 10 0 0 0 0 0 0 0 0 4
Southern North Sea blue 3 10 2 0 3 3 4 3 20 73 79 20
green 85 84 95 100 96 97 95 97 79 0 0 73
orange 0 0 0 0 0 0 0 0 0 27 21 5
red 12 6 3 0 1 0 1 0 1 0 0 2
Channel blue 9 12 4 0 12 8 4 8 14 28 46 14
green 62 59 56 100 72 80 67 78 76 0 0 56
orange 0 0 0 0 0 0 0 0 0 72 54 13
red 29 29 40 0 16 12 29 14 10 0 0 17
total blue 14 17 10 0 12 10 10 11 22 57 64 22
green 68 68 75 100 82 86 80 85 74 0 0 63
orange 0 0 0 0 0 0 0 0 0 43 36 8
red 18 15 15 0 6 4 10 4 4 0 0 7
3 Irish and Scottish West Coast blue 11 44 56 0 67 56 45 33 67 89 89 52
green 89 56 44 100 33 44 44 67 33 0 0 45
orange 0 0 0 0 0 0 0 0 0 11 11 2
red 0 0 0 0 0 0 11 0 0 0 0 1
Irish Sea blue 0 0 0 0 0 0 0 0 0 21 32 5
green 95 84 89 100 95 89 89 89 89 0 0 74
orange 0 0 0 0 0 0 0 0 0 79 68 14
red 5 16 11 0 5 11 11 11 11 0 0 7
Celtic Sea blue 0 20 0 0 20 20 20 20 40 40 60 25
green 75 80 75 100 80 80 80 80 60 0 0 61
orange 0 0 0 0 0 0 0 0 0 60 40 10
red 25 0 25 0 0 0 0 0 0 0 0 4
total blue 3 15 16 0 21 18 15 12 24 42 52 21
green 91 76 75 100 76 76 76 82 70 0 0 64
orange 0 0 0 0 0 0 0 0 0 58 48 10
red 6 9 9 0 3 6 9 6 6 0 0 5
4 Iberian Coast blue 11 9 20 23 15 29 32 29 26 22
green 63 61 63 66 59 54 57 0 0 47
orange 0 0 0 0 0 0 0 71 74 16
red 26 30 17 11 26 17 11 0 0 15
Gulf of Cadiz blue 72 8 72 64 52 72 67 54 72 59
green 24 88 24 32 44 24 29 0 0 29
orange 0 0 0 0 0 0 0 46 28 9
red 4 4 4 4 4 4 4 0 0 3
total blue 36 9 42 40 30 47 46 39 46 37
green 47 72 47 52 53 42 46 0 0 40
orange 0 0 0 0 0 0 0 61 54 13
red 17 19 11 8 17 11 8 0 0 10


Regional assessment - methods

Tabulating the number of time series with each status category by region provides a quick summary of the individual time series results. However, it does not provide an objective regional assessment of status. Similarly, tabulating the number of time series with an upward or downward trend does not provide an objective regional assessment of trend. This section describes how the individual time series results can by synthesised in a meta-analysis to assess both status and trend at the regional level.

Trends

For a regional trend assessment, the trend in each time series is summarised by the estimated change in log concentration over the last twenty years (or shorter if the time series doesn’t extend that far back). Regional trends are then estimated by fitting the following linear mixed model by restricted maximum likelihood:

  • response: trend (yearly change in log concentration)
  • fixed model: region
  • random model: PAH + region.PAH + station + trend estimation variation + residual variation

The fixed model means that a trend is estimated for each region. Trends in the different PAHs are assumed to be broadly similar, because inputs and control measures are likely to affect all PAHs in a similar way. Each regional trend can thus be interpreted as the common trend in PAH concentrations in that region (i.e. the trend averaged across all PAHs).

The random model has five terms:

  • PAH allows for variation in trend between PAHs common to all regions
  • region.PAH allows for additional variation in trend between PAHs within regions
  • station allows for variation in trend between stations common to all PAHs
  • trend estimation variation is the variance of the trend estimates from the individual time series analysis, assumed known and fixed
  • residual variation is the variation that cannot be explained by any of the fixed effects or the other random effects

The meta-analysis is restricted to time series from monitoring stations that are classified as ‘representative’ or ‘baseline’ (near pristine conditions or only subject to very diffuse inputs). ‘Impacted’ stations (those close to a point source) are omitted because trends there will likely reflect changes due to the point source and will be ‘unrepresentative’ at the regional level.

The meta-analysis is further restricted to:

  • regions with at least three trend stations with good geographic spread. Three stations is considered the minimum required to provide some sort of evidence base at the regional level
  • PAHs with trend information for at least three stations (over all regions): PAHs are treated as random effects in the meta-anlaysis, so information about trends in one PAH can be ‘borrowed’ from the trend information in the other PAHs

Status

For a regional status assessment, the status of each time series is summarised by the difference between the estimated mean log concentration in the final monitoring year and the log assessment concentration. This ensures that status is always measured on the same scale, even though the assessment concentration might vary between PAHs and regions. Essentially the same linear mixed model as for trends is then fitted:

  • response: status (mean log concentration - log assessment concentration)
  • fixed model: region
  • random model: PAH + region.PAH + station + status estimation variation + residual variation

where status estimation variation is the variation in the status estimates from the individual time series analysis, assumed known and fixed.

There are no restrictions on the time series used in the status meta-analysis based on the classification of the monitoring station; time series from baseline, representative and impacted stations are all included. However, the few time series with a non-parametric assessment of status must be excluded, because there is no summary measure of status to use in the mixed model.

Again, the meta-analysis is restricted to regions with at least three status stations with good geographic spread and to PAHs with status information for at least three stations (over all regions).

Presentation

The results of both the trend and status regional assessments are back-transformed for presentation. The estimated regional trend is then interpreted as the percentage yearly change in concentration and the estimated regional status as the ratio of the mean regional concentration to the assessment concentration. To illustrate the latter, a value of 1 indicates that the mean regional concentration is equal to the assessment concentration; a value of 0.5 indicates that it is half the assessment concentration, and a value of 2 indicates that it is twice the assessment concentration.


Regional assessment - availability of time series

This section provides more detail on the number and geographic spread of the time series available for the meta-analyses. The tabs show the stations with parametric trend and status assessments for each OSPAR region in turn, having excluded trend assessments at impacted stations. The purple circles are stations where there is a trend assessment for at least one PAH, and the light blue cirles are stations where there are only status assessments.

The following regions have an insufficient number of time series or spread of stations and are excluded from the regional assessment:

  • trend: Celtic Sea
  • status:


OSPAR region 1


OSPAR region 2


OSPAR region 3


OSPAR region 4


Regional trends

The first 4 tabs show:

  • Regional trends: estimates of the regional trend (averaged over PAHs) with pointwise 95% confidence intervals
  • Regional trends by PAH: regional trend estimates for each PAH with pointwise 95% confidence intervals plotted by PAH
  • Regional trends by region: regional trend estimates for each PAH with pointwise 95% confidence intervals plotted by region
  • Individual time series: the trend estimates from the individual time series on which the regional assessment is based. The estimates for regions with insufficient geographic spread (and excluded from the meta-analysis) are also shown.

The symbols in all these plots have the following interpretation:

  • downward triangle: the mean concentration is significantly decreasing (p < 0.05)
  • circle: there is no significant change in mean concentration (p > 0.05)
  • upward triangle: the mean concentration is significantly increasing (p < 0.05)

The final 2 tabs show the estimates of the regional trend (averaged over PAHs) and the regional trend by PAH


Regional trends


Regional trends by PAH


Regional trends by region


Individual time series


Estimates by region

This table shows the estimates of the regional trend:

  • trend: the estimated mean yearly change in log concentration across the region (multiplied by 100 for presentation)
  • se: the corresponding standard error
  • lower, upper: the corresponding pointwise 95% confidence limits
  • % yearly change: the estimated mean % yearly change in concentration across the region
  • %yc lower, %yc upper: the corresponding pointwise 95% confidence limits


MIME region trend se lower upper % yearly change %yc lower %yc upper
Northern North Sea -0.93 0.89 -2.67 0.82 -0.92 -2.63 0.82
Southern North Sea -0.88 0.52 -1.89 0.13 -0.88 -1.87 0.13
Channel -4.90 2.02 -8.86 -0.94 -4.78 -8.48 -0.94
Irish and Scottish West Coast 2.33 1.36 -0.34 5.00 2.35 -0.34 5.12
Irish Sea -1.96 1.01 -3.95 0.03 -1.94 -3.87 0.03
Gulf of Cadiz -1.97 1.02 -3.96 0.02 -1.95 -3.89 0.02


Estimates by region and PAH

This table shows the estimates of the regional trend by determinand:

  • trend: the estimated mean yearly change in log concentration across the region (multiplied by 100 for presentation)
  • se: the corresponding standard error
  • lower, upper: the corresponding pointwise 95% confidence limits
  • % yearly change: the estimated mean % yearly change in concentration across the region
  • %yc lower, %yc upper: the corresponding pointwise 95% confidence limits


MIME region PAH trend se lower upper % yearly change %yc lower %yc upper
Northern North Sea NAP -1.79 1.01 -3.77 0.18 -1.78 -3.70 0.18
ACNLE -1.48 1.21 -3.84 0.89 -1.47 -3.77 0.89
ACNE -0.86 1.02 -2.86 1.13 -0.86 -2.81 1.14
FLE -1.09 0.95 -2.96 0.77 -1.09 -2.92 0.78
PA -0.77 0.94 -2.61 1.07 -0.77 -2.58 1.07
ANT -0.98 0.99 -2.91 0.95 -0.98 -2.87 0.95
DBT -1.06 1.02 -3.06 0.94 -1.05 -3.02 0.95
FLU -0.55 0.94 -2.39 1.30 -0.54 -2.36 1.31
PYR -0.67 0.95 -2.52 1.18 -0.67 -2.49 1.19
BAA -0.85 0.94 -2.70 1.00 -0.85 -2.66 1.00
CHR -1.68 0.96 -3.56 0.20 -1.66 -3.49 0.20
BAP -0.68 0.95 -2.53 1.18 -0.67 -2.50 1.19
BEP -0.71 0.94 -2.56 1.14 -0.71 -2.53 1.14
BBKF -1.64 0.96 -3.52 0.24 -1.63 -3.46 0.24
DBAHA -0.99 1.00 -2.95 0.98 -0.98 -2.91 0.98
PER -0.94 1.00 -2.89 1.01 -0.94 -2.85 1.02
BGHIP -0.31 0.95 -2.18 1.55 -0.31 -2.16 1.57
ICDP 0.36 0.97 -1.53 2.26 0.36 -1.52 2.28
Southern North Sea NAP 0.30 0.53 -0.73 1.34 0.31 -0.72 1.34
ACNLE 0.32 0.81 -1.28 1.91 0.32 -1.27 1.93
ACNE -1.75 0.59 -2.90 -0.59 -1.73 -2.86 -0.59
FLE -0.08 0.55 -1.15 0.99 -0.08 -1.14 1.00
PA -0.24 0.48 -1.19 0.71 -0.24 -1.18 0.71
ANT 0.54 0.49 -0.42 1.51 0.55 -0.42 1.52
FLU -1.11 0.48 -2.05 -0.17 -1.10 -2.03 -0.17
PYR -1.23 0.48 -2.17 -0.29 -1.22 -2.14 -0.29
BAA -1.08 0.48 -2.02 -0.14 -1.08 -2.00 -0.14
CHR -1.06 0.48 -2.00 -0.12 -1.06 -1.98 -0.12
BAP -1.27 0.48 -2.22 -0.32 -1.27 -2.20 -0.32
BEP -1.05 0.49 -2.01 -0.09 -1.04 -1.99 -0.09
BBKF -1.30 0.48 -2.25 -0.35 -1.29 -2.22 -0.35
DBAHA -0.70 0.50 -1.69 0.28 -0.70 -1.67 0.28
PER -1.73 0.70 -3.10 -0.37 -1.72 -3.05 -0.37
BGHIP -1.60 0.48 -2.53 -0.67 -1.59 -2.50 -0.67
ICDP -1.92 0.48 -2.86 -0.98 -1.90 -2.82 -0.97
Channel NAP -4.78 2.16 -9.01 -0.55 -4.67 -8.62 -0.55
ACNLE -3.89 2.21 -8.22 0.44 -3.82 -7.89 0.44
ACNE -4.30 2.20 -8.61 0.00 -4.21 -8.25 0.00
FLE -5.06 2.15 -9.28 -0.84 -4.93 -8.87 -0.83
PA -5.14 2.13 -9.31 -0.97 -5.01 -8.89 -0.97
ANT -4.89 2.15 -9.10 -0.67 -4.77 -8.70 -0.67
DBT -5.07 2.23 -9.43 -0.70 -4.94 -9.00 -0.70
FLU -5.08 2.16 -9.32 -0.85 -4.96 -8.90 -0.85
PYR -5.14 2.15 -9.35 -0.93 -5.01 -8.93 -0.93
BAA -4.89 2.20 -9.21 -0.58 -4.77 -8.79 -0.58
CHR -5.25 2.20 -9.56 -0.93 -5.11 -9.12 -0.93
BAP -5.00 2.15 -9.21 -0.79 -4.88 -8.80 -0.79
BEP -5.43 2.14 -9.63 -1.23 -5.29 -9.18 -1.23
BBKF -5.67 2.15 -9.89 -1.46 -5.51 -9.41 -1.45
DBAHA -4.46 2.17 -8.70 -0.21 -4.36 -8.34 -0.21
PER -5.53 2.14 -9.73 -1.34 -5.38 -9.27 -1.33
BGHIP -4.46 2.14 -8.66 -0.26 -4.36 -8.29 -0.26
ICDP -4.20 2.16 -8.43 0.04 -4.11 -8.08 0.04
Irish and Scottish West Coast NAP 1.83 1.50 -1.11 4.77 1.85 -1.10 4.89
ACNLE 2.36 1.64 -0.86 5.58 2.39 -0.85 5.73
ACNE 2.42 1.53 -0.58 5.42 2.45 -0.58 5.57
FLE 2.48 1.48 -0.43 5.38 2.51 -0.43 5.53
PA 2.79 1.47 -0.10 5.67 2.83 -0.10 5.83
ANT 2.57 1.51 -0.39 5.52 2.60 -0.39 5.67
DBT 2.95 1.47 0.07 5.84 3.00 0.07 6.01
FLU 1.64 1.47 -1.23 4.51 1.66 -1.22 4.62
PYR 2.54 1.47 -0.34 5.42 2.57 -0.34 5.57
BAA 1.79 1.49 -1.13 4.71 1.80 -1.12 4.82
CHR 2.36 1.47 -0.51 5.23 2.39 -0.51 5.37
BAP 2.36 1.47 -0.52 5.24 2.39 -0.52 5.38
BEP 3.03 1.47 0.15 5.92 3.08 0.15 6.10
BBKF 1.72 1.45 -1.13 4.56 1.73 -1.12 4.66
DBAHA 2.13 1.45 -0.71 4.98 2.16 -0.71 5.10
PER 1.81 1.47 -1.07 4.68 1.82 -1.06 4.79
BGHIP 2.53 1.46 -0.33 5.40 2.56 -0.33 5.55
ICDP 2.58 1.46 -0.27 5.44 2.62 -0.27 5.59
Irish Sea NAP -2.11 1.10 -4.28 0.05 -2.09 -4.19 0.05
ACNLE -1.55 1.13 -3.76 0.66 -1.54 -3.69 0.66
ACNE -1.57 1.15 -3.81 0.68 -1.55 -3.74 0.68
FLE -2.09 1.12 -4.28 0.10 -2.07 -4.19 0.10
PA -1.28 1.07 -3.37 0.81 -1.27 -3.32 0.81
ANT -2.51 1.09 -4.66 -0.37 -2.48 -4.55 -0.37
DBT -2.35 1.12 -4.55 -0.15 -2.32 -4.45 -0.15
FLU -1.67 1.06 -3.75 0.42 -1.65 -3.68 0.42
PYR -1.54 1.06 -3.63 0.54 -1.53 -3.56 0.54
BAA -2.33 1.08 -4.44 -0.22 -2.30 -4.34 -0.22
CHR -1.84 1.09 -3.98 0.29 -1.82 -3.90 0.29
BAP -1.42 1.08 -3.54 0.70 -1.41 -3.47 0.70
BEP -1.76 1.07 -3.86 0.34 -1.74 -3.79 0.34
BBKF -2.80 1.08 -4.91 -0.69 -2.76 -4.79 -0.69
DBAHA -2.34 1.08 -4.46 -0.22 -2.31 -4.37 -0.22
PER -3.69 1.08 -5.82 -1.56 -3.62 -5.65 -1.55
BGHIP -1.19 1.08 -3.31 0.93 -1.19 -3.26 0.93
ICDP -1.21 1.08 -3.32 0.90 -1.21 -3.27 0.90
Gulf of Cadiz PA -1.37 1.07 -3.47 0.73 -1.36 -3.41 0.73
ANT 1.61 1.15 -0.64 3.86 1.62 -0.64 3.93
FLU -4.16 1.09 -6.29 -2.02 -4.07 -6.10 -2.00
PYR -4.18 1.11 -6.35 -2.01 -4.10 -6.16 -1.99
BAA -1.23 1.13 -3.45 1.00 -1.22 -3.39 1.00
CHR -1.96 1.11 -4.15 0.22 -1.95 -4.06 0.22
BAP -2.26 1.11 -4.43 -0.10 -2.24 -4.33 -0.10
BEP -2.21 1.14 -4.45 0.03 -2.19 -4.36 0.03
BBKF -1.05 1.12 -3.25 1.15 -1.04 -3.19 1.15
DBAHA -0.63 1.22 -3.03 1.76 -0.63 -2.98 1.77
BGHIP -2.01 1.13 -4.22 0.20 -1.99 -4.13 0.20
ICDP -4.19 1.08 -6.31 -2.06 -4.10 -6.12 -2.04


Regional status compared to the Effects Range Low (ERL)

The first 4 tabs show:

  • Regional status: estimates of the regional status (averaged over PAHs) with pointwise upper one-sided 95% confidence intervals
  • Regional status by PAH: regional status estimates for each PAH with pointwise upper one-sided 95% confidence intervals plotted by PAH
  • Regional status by region: regional status estimates for each PAH with pointwise upper one-sided 95% confidence intervals plotted by region
  • Individual time series: the status estimates from the individual time series on which the regional assessment is based. The estimates for regions with insufficient geographic spread (and excluded from the meta-analysis) are also shown.

The symbols in all the plots have the following interpretation:

  • blue: the mean concentration is significantly (p < 0.05) below the Background Assessment Concentration (BAC)
  • green: the mean concentration is significantly (p < 0.05) below the ERL
  • red: the mean concentration is not significantly below the ERL

Note that to see why some points might be coloured blue, it is necessary to look ahead to the next section, where status is compared to the BAC. Unfortunately, it isn’t easy to present the assessment of status relative to the ERL with the assessment of status relative to the BAC because the ratio of the BAC to the ERL can vary between PAHs and regions.

The final 2 tabs show the estimates of the regional status (averaged over PAHs) and the regional status trend by PAH


Regional status


Regional status by PAH


Regional status by region


Individual time series


Estimates by region

This table shows the estimates of the regional status:

  • status: the estimated mean log concentration minus the log ERL
  • se: the corresponding standard error
  • upper: the corresponding pointwise upper one-sided 95% confidence limit
  • concentration: the estimated mean concentration relative to the ERL
  • conc upper: the corresponding pointwise upper one-sided 95% confidence limit


MIME region status se upper concentration conc upper
Northern North Sea -3.28 0.30 -2.79 0.04 0.06
Southern North Sea -2.42 0.22 -2.06 0.09 0.13
Channel -2.50 0.24 -2.11 0.08 0.12
Irish and Scottish West Coast -3.11 0.40 -2.45 0.04 0.09
Irish Sea -1.94 0.31 -1.43 0.14 0.24
Celtic Sea -3.02 0.51 -2.17 0.05 0.11
Iberian Coast -2.77 0.26 -2.34 0.06 0.10
Gulf of Cadiz -4.85 0.28 -4.39 0.01 0.01


Estimates by region and PAH

This table shows the estimates of the regional trend by determinand:

  • status: the estimated mean log concentration minus the log ERL
  • se: the corresponding standard error
  • upper: the corresponding pointwise upper one-sided 95% confidence limit
  • concentration: the estimated mean concentration relative to the ERL
  • conc upper: the corresponding pointwise upper one-sided 95% confidence limit


MIME region PAH status se upper concentration conc upper
Northern North Sea NAP -3.27 0.24 -2.87 0.04 0.06
PA -2.50 0.24 -2.10 0.08 0.12
ANT -3.28 0.24 -2.89 0.04 0.06
DBT -4.62 0.24 -4.22 0.01 0.01
FLU -3.20 0.24 -2.81 0.04 0.06
PYR -3.48 0.24 -3.08 0.03 0.05
BAA -2.98 0.24 -2.58 0.05 0.08
CHR -3.17 0.24 -2.77 0.04 0.06
BAP -3.07 0.24 -2.68 0.05 0.07
BGHIP
ICDP
Southern North Sea NAP -2.18 0.12 -1.99 0.11 0.14
PA -1.69 0.11 -1.50 0.19 0.22
ANT -2.10 0.11 -1.91 0.12 0.15
DBT -3.57 0.15 -3.31 0.03 0.04
FLU -2.27 0.11 -2.08 0.10 0.13
PYR -2.66 0.11 -2.48 0.07 0.08
BAA -2.26 0.11 -2.08 0.10 0.13
CHR -2.44 0.11 -2.25 0.09 0.11
BAP -2.63 0.11 -2.44 0.07 0.09
BGHIP
ICDP
Channel NAP -2.94 0.17 -2.67 0.05 0.07
PA -1.87 0.16 -1.61 0.15 0.20
ANT -2.08 0.16 -1.82 0.12 0.16
DBT -3.88 0.19 -3.56 0.02 0.03
FLU -2.33 0.16 -2.07 0.10 0.13
PYR -2.66 0.16 -2.40 0.07 0.09
BAA -2.04 0.16 -1.78 0.13 0.17
CHR -2.38 0.16 -2.12 0.09 0.12
BAP -2.36 0.16 -2.10 0.09 0.12
BGHIP
ICDP
Irish and Scottish West Coast NAP -2.85 0.37 -2.24 0.06 0.11
PA -2.19 0.36 -1.59 0.11 0.20
ANT -3.28 0.37 -2.68 0.04 0.07
DBT -4.09 0.37 -3.48 0.02 0.03
FLU -3.10 0.36 -2.50 0.04 0.08
PYR -3.44 0.36 -2.84 0.03 0.06
BAA -2.98 0.37 -2.38 0.05 0.09
CHR -2.93 0.36 -2.33 0.05 0.10
BAP -3.08 0.36 -2.48 0.05 0.08
BGHIP
ICDP
Irish Sea NAP -1.77 0.25 -1.35 0.17 0.26
PA -1.13 0.25 -0.71 0.32 0.49
ANT -1.82 0.25 -1.40 0.16 0.25
DBT -3.37 0.26 -2.94 0.03 0.05
FLU -1.88 0.25 -1.46 0.15 0.23
PYR -2.06 0.25 -1.65 0.13 0.19
BAA -1.66 0.25 -1.25 0.19 0.29
CHR -1.88 0.25 -1.47 0.15 0.23
BAP -1.90 0.25 -1.48 0.15 0.23
BGHIP
ICDP
Celtic Sea NAP -2.78 0.50 -1.96 0.06 0.14
PA -2.27 0.49 -1.46 0.10 0.23
ANT -2.74 0.50 -1.92 0.06 0.15
DBT -4.08 0.51 -3.25 0.02 0.04
FLU -2.90 0.49 -2.10 0.05 0.12
PYR -3.32 0.49 -2.52 0.04 0.08
BAA -2.83 0.49 -2.03 0.06 0.13
CHR -3.03 0.49 -2.23 0.05 0.11
BAP -3.19 0.49 -2.38 0.04 0.09
BGHIP
ICDP
Iberian Coast PA -1.97 0.19 -1.67 0.14 0.19
ANT -2.27 0.19 -1.96 0.10 0.14
FLU -2.58 0.18 -2.28 0.08 0.10
PYR -2.98 0.18 -2.67 0.05 0.07
BAA -2.47 0.19 -2.16 0.08 0.11
CHR -3.02 0.19 -2.71 0.05 0.07
BAP -2.98 0.18 -2.68 0.05 0.07
BGHIP
ICDP
Gulf of Cadiz PA -4.31 0.22 -3.96 0.01 0.02
ANT -4.33 0.22 -3.97 0.01 0.02
FLU -4.86 0.22 -4.50 0.01 0.01
PYR -5.06 0.22 -4.70 0.01 0.01
BAA -4.41 0.22 -4.05 0.01 0.02
CHR -4.98 0.22 -4.62 0.01 0.01
BAP -4.91 0.22 -4.55 0.01 0.01
BGHIP
ICDP


Regional status compared to the Background Assessment Concentration (BAC)

The first 4 tabs show:

  • Regional status: estimates of the regional status (averaged over PAHs) with pointwise upper one-sided 95% confidence intervals
  • Regional status by PAH: regional status estimates for each PAH with pointwise upper one-sided 95% confidence intervals plotted by PAH
  • Regional status by region: regional status estimates for each PAH with pointwise upper one-sided 95% confidence intervals plotted by region
  • Individual time series: the status estimates from the individual time series on which the regional assessment is based. The estimates for regions with insufficient geographic spread (and excluded from the meta-analysis) are also shown.

The symbols in all the plots have the following interpretation:

  • blue: the mean concentration is significantly (p < 0.05) below the BAC
  • green: the mean concentration is significantly (p < 0.05) below the Effects Range Low (ERL)
  • orange: there is no ERL and the mean concentration is not significantly below the BAC
  • red: the mean concentration is not significantly below the ERL

The final 2 tabs show the estimates of the regional status (averaged over PAHs) and the regional status trend by PAH


Regional status


Regional status by PAH


Regional status by region


Individual time series


Estimates by region

This table shows the estimates of the regional status:

  • status: the estimated mean log concentration minus the log BAC
  • se: the corresponding standard error
  • upper: the corresponding pointwise upper one-sided 95% confidence limit
  • concentration: the estimated mean concentration relative to the BAC
  • conc upper: the corresponding pointwise upper one-sided 95% confidence limit


MIME region status se upper concentration conc upper
Northern North Sea -0.35 0.26 0.09 0.70 1.09
Southern North Sea 0.23 0.17 0.52 1.26 1.68
Channel 0.21 0.20 0.54 1.23 1.71
Irish and Scottish West Coast -0.33 0.37 0.28 0.72 1.33
Irish Sea 0.78 0.27 1.23 2.18 3.43
Celtic Sea -0.33 0.48 0.47 0.72 1.59
Iberian Coast 1.18 0.23 1.55 3.25 4.70
Gulf of Cadiz -0.87 0.25 -0.47 0.42 0.63


Estimates by region and PAH

This table shows the estimates of the regional trend by determinand:

  • status: the estimated mean log concentration minus the log BAC
  • se: the corresponding standard error
  • upper: the corresponding pointwise upper one-sided 95% confidence limit
  • concentration: the estimated mean concentration relative to the BAC
  • conc upper: the corresponding pointwise upper one-sided 95% confidence limit


MIME region PAH status se upper concentration conc upper
Northern North Sea NAP -0.26 0.24 0.13 0.77 1.14
PA -0.44 0.24 -0.06 0.64 0.95
ANT -0.45 0.24 -0.06 0.64 0.94
DBT
FLU -0.45 0.24 -0.06 0.64 0.94
PYR -0.14 0.24 0.25 0.87 1.28
BAA -0.15 0.24 0.24 0.86 1.27
CHR -0.17 0.24 0.21 0.84 1.24
BAP -0.39 0.23 -0.00 0.68 1.00
BGHIP -0.50 0.23 -0.11 0.61 0.90
ICDP -0.56 0.24 -0.17 0.57 0.84
Southern North Sea NAP 0.83 0.11 1.02 2.29 2.76
PA 0.33 0.11 0.52 1.39 1.67
ANT 0.74 0.11 0.92 2.09 2.51
DBT
FLU 0.47 0.11 0.65 1.60 1.92
PYR 0.66 0.11 0.84 1.93 2.32
BAA 0.53 0.11 0.71 1.69 2.03
CHR 0.52 0.11 0.70 1.68 2.02
BAP 0.04 0.11 0.22 1.04 1.25
BGHIP -0.79 0.11 -0.61 0.45 0.55
ICDP -0.99 0.11 -0.81 0.37 0.45
Channel NAP -0.02 0.16 0.25 0.98 1.29
PA 0.14 0.15 0.39 1.15 1.48
ANT 0.75 0.16 1.01 2.12 2.75
DBT
FLU 0.40 0.15 0.65 1.49 1.92
PYR 0.66 0.15 0.91 1.93 2.49
BAA 0.75 0.15 1.00 2.11 2.72
CHR 0.57 0.15 0.82 1.77 2.28
BAP 0.31 0.15 0.56 1.36 1.76
BGHIP -0.69 0.15 -0.43 0.50 0.65
ICDP -0.78 0.15 -0.53 0.46 0.59
Irish and Scottish West Coast NAP 0.11 0.36 0.71 1.12 2.02
PA -0.19 0.36 0.40 0.83 1.49
ANT -0.57 0.36 0.02 0.56 1.02
DBT
FLU -0.41 0.36 0.17 0.66 1.19
PYR -0.18 0.36 0.41 0.83 1.50
BAA -0.25 0.36 0.34 0.78 1.40
CHR 0.02 0.36 0.61 1.02 1.83
BAP -0.45 0.36 0.14 0.64 1.15
BGHIP -0.62 0.36 -0.03 0.54 0.97
ICDP -0.71 0.36 -0.12 0.49 0.88
Irish Sea NAP 1.21 0.25 1.62 3.35 5.05
PA 0.88 0.25 1.29 2.41 3.62
ANT 0.99 0.25 1.40 2.69 4.04
DBT
FLU 0.83 0.25 1.24 2.30 3.45
PYR 1.24 0.25 1.65 3.47 5.21
BAA 1.10 0.25 1.51 3.01 4.51
CHR 1.05 0.25 1.45 2.85 4.28
BAP 0.76 0.25 1.16 2.13 3.20
BGHIP -0.04 0.25 0.37 0.96 1.44
ICDP -0.21 0.25 0.20 0.81 1.22
Celtic Sea NAP 0.26 0.49 1.07 1.29 2.91
PA -0.24 0.48 0.55 0.79 1.73
ANT 0.06 0.49 0.87 1.07 2.39
DBT
FLU -0.18 0.48 0.61 0.84 1.83
PYR -0.06 0.48 0.73 0.94 2.08
BAA -0.09 0.48 0.70 0.91 2.00
CHR -0.11 0.48 0.68 0.90 1.98
BAP -0.57 0.48 0.23 0.57 1.26
BGHIP -1.17 0.48 -0.38 0.31 0.69
ICDP -1.19 0.48 -0.40 0.30 0.67
Iberian Coast PA 1.53 0.18 1.83 4.62 6.22
ANT 1.61 0.18 1.91 4.98 6.73
FLU 1.15 0.18 1.45 3.16 4.26
PYR 1.10 0.18 1.40 3.01 4.05
BAA 1.15 0.18 1.45 3.16 4.25
CHR 0.82 0.19 1.12 2.26 3.07
BAP 0.97 0.18 1.26 2.63 3.54
BGHIP 1.02 0.18 1.31 2.77 3.72
ICDP 0.99 0.18 1.29 2.69 3.62
Gulf of Cadiz PA -0.84 0.21 -0.49 0.43 0.61
ANT -0.45 0.22 -0.10 0.64 0.91
FLU -1.13 0.21 -0.78 0.32 0.46
PYR -0.98 0.21 -0.63 0.37 0.53
BAA -0.79 0.21 -0.44 0.46 0.65
CHR -1.12 0.21 -0.77 0.33 0.46
BAP -0.96 0.21 -0.61 0.38 0.54
BGHIP -0.75 0.21 -0.40 0.47 0.67
ICDP -1.11 0.21 -0.76 0.33 0.47


PAH profiles

The profile of concentrations across PAHs can sometimes be useful for examining sources, and for comparing concentrations across regions where assessment criteria are not available. Profiles were examined by fitting the following linear mixed model by restricted maximum likelihood:

  • response: mean log concentration
  • fixed model: region
  • random model: PAH + region.PAH + station + estimation variation + residual variation

where, for each time series, the mean log concentration is the estimated mean log concentration in the final monitoring year and the estimation variance is the variance associated with this estimate.

The estimated PAH concentration profiles by region are shown below with pointwise 95% confidence limits. The units are ug/kg dw normalised to 2.5% organic carbon (apart from in the Iberian Coast and Gulf of Cadiz where they are non-normalised).